Meaning
Permanent or temporary increase in the equivalent series resistance of an electrolytic capacitor caused by thermal cycling across the freezing point of its electrolyte. In ruggedized electronic designs, freeze-thaw esr shift alters the impedance of power filters, which can lead to increased voltage ripple in outdoor sensing equipment. The severity of the shift depends on the chemical composition and moisture content of the internal electrolyte.
Capacitor Degradation
Repeating phase changes of the liquid electrolyte exert physical stress on the internal seals and electrode foils of the component. Microscopic cracks can develop, allowing the volatile compounds to escape over time. This slow loss of electrolyte results in a progressive and irreversible increase in resistance.
Circuit Impact
High resistance in the filtering stage reduces the component’s ability to smooth out voltage fluctuations. Deeper voltage dips result from transient load changes. The efficiency of the power converter also drops due to thermal losses.
Product Qualification
Testing for this effect involves subjecting prototype assemblies to multiple thermal cycles in specialized environmental chambers. Engineers measure the impedance of critical capacitors before and after the exposure to confirm they remain within specified tolerance limits. Choosing high-grade polymer capacitors with solid electrolytes is a common method used to avoid this phenomenon entirely.