Meaning
Molecular response to an oscillating electric field involves a time-dependent lag in the orientation of permanent dipoles. Dipolar relaxation occurs when the frequency of the applied field exceeds the rate at which polar molecules can reorient themselves. This delay leads to a decrease in the dielectric constant as the frequency increases.
The effect is most prominent in the microwave region where the molecular inertia becomes a limiting factor for alignment.
Dispersion Effect
Changes in the dielectric properties over a wide frequency range characterize the dispersion associated with this phenomenon. The permittivity drops from a static value to a high-frequency limit as the dipoles cease to track the field. Material selection for high-speed boards depends on identifying the frequency where dipolar relaxation starts to degrade signal integrity.
Energy Dissipation
Frictional forces during the attempted rotation of molecules convert electrical energy into heat. This loss is quantified by the dissipation factor or loss tangent of the material. Dielectric heating is a direct consequence of this energy transfer within the substrate.
Frequency Sensitivity
Signal attenuation increases as the operating frequency approaches the relaxation time of the polymer chains. Resins with low dipole moments are preferred for applications operating in the millimeter-wave bands. Designers specify these materials to maintain consistent phase velocity across the bandwidth of the system.