Meaning
Evolution of chemical layers formed between two different metals through solid state diffusion at a shared boundary. In electronic assemblies, intermetallic growth typically occurs at the interface between the solder alloy and the copper pads of a printed circuit board. This process is continuous over the life of the device and gradually changes the mechanical and electrical properties of the joint.
Bond Formation
Initial contact during the soldering process creates a thin layer that provides the necessary adhesion for a strong electrical connection. A controlled amount of intermetallic growth is desirable because it signifies that the metals have fused correctly. Common layers include tin-copper compounds that provide the structural backbone of the solder joint.
Without this chemical bond, the assembly would be prone to mechanical separation during handling.
Interface Brittleness
Excessive thickness of the reaction layer leads to a reduction in the ductility of the connection. While the intermetallic growth starts as a beneficial bond, a layer that is too thick becomes brittle and sensitive to vibration or thermal cycling. This transformation is a common cause of failure in portable devices that are dropped or exposed to frequent temperature swings.
High stress concentrated at the interface can lead to cracks that propagate through the entire joint.
Temperature Acceleration
Rate of diffusion increases at a higher rate as the ambient temperature of the device rises. Continuous operation of high power components drives intermetallic growth at a faster pace than in devices that remain cool. Storage conditions also play a role, as long term exposure to heat will thicken the layers even when the device is not in use.
Reliable design accounts for this aging process by selecting plating materials that slow down the diffusion rate. Nickel barriers are often placed between the copper and the gold or tin to act as a shield.