Meaning
High temperature reactions in oxygen rich furnaces convert silicon surfaces into high purity insulating dioxide layers. During thermal oxidation the substrate is exposed to controlled atmospheres at temperatures that facilitate the diffusion of molecules into the lattice. This grown layer features lower defect densities than any deposited alternative because it is formed from the substrate itself.
Diffusion Rate
Wafer temperature and gas pressure dictate exactly how far the reaction extends into the material over time. In thermal oxidation the thickness of the insulator is self consistent across the entire diameter of the batch. Higher humidity levels during wet growth increase the speed but can decrease the physical density of the oxide.
Interface Quality
Bonding happens directly between the silicon and the growing oxygen structure with very low surface roughness. Through thermal oxidation the engineer minimizes the trapped charge that would otherwise interfere with the control of the electrical channel. Dense films act as effective hard masks for subsequent etching or ion implantation.
Structural Load
High heat can introduce mechanical stresses if the temperature change happens too rapidly for the substrate to handle. Correct thermal oxidation incorporates a steady ramp up and ramp down to prevent the formation of crystal dislocations or warping. This care maintains the physical integrity of the entire wafer during initial fabrication steps.